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i don't see how "Just" tom puree can get to the sauce taste - i've tried many ideas as i've said.
this powdery taste seems to only occur with some spices ie paprika & chilli (maybe others i don't know). it does not happen with say curry powder.
I think an important lesson is if you want it hotter, get a hotter chilli powder rather than piling in loads of a milder chilli powder.
take the pan off the heat before adding your spice blend and chilli powder.
my interest is solely in paprika....